Critical behaviour of the Rouse model for gelling polymers

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Critical behaviour of the Rouse model for gelling polymers

It is shown that the traditionally accepted “Rouse values” for the critical exponents at the gelation transition do not arise from the Rouse model for gelling polymers. The true critical behaviour of the Rouse model for gelling polymers is obtained from spectral properties of the connectivity matrix of the fractal clusters that are formed by the molecules. The required spectral properties are r...

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ژورنال

عنوان ژورنال: Journal of Physics A: Mathematical and General

سال: 2003

ISSN: 0305-4470,1361-6447

DOI: 10.1088/0305-4470/36/42/002